EFFECTS OF GRAPHENE NANOPLATELETS AT LOW FILLER CONTENT ON TENSILE AND FRACTURE TOUGHNESS PROPERTIES OF F-GNP/EPOXY NANOCOMPOSITES
Keywords:
PALF fiber, , Mechanical properties, Dynamic Analysis, FTIR, Water absorptionAbstract
This paper aims at effects of graphene nanoplatelets at low filler content on tensile and fracture toughness properties of plasma functionalized graphene nanoplatelets f-GNP/epoxy nanocomposites. Various mechanical tests were performed on a series of f-GNP/epoxy at low nanofiller loading to assess the effect of the nanofiller on mechanical properties. Most importantly, a significant enhancement in fracture toughness is achieved without compromising the tensile and thermal properties of the nanocomposites. The fracture toughness of neat epoxy resin was increased by over 50 % with the incorporation of 0.25 wt% f-GNP loading, obtaining a value of 245 , while the neat epoxy indicated a value of 162 . The glass transition temperature and coefficient of thermal expansion (CTE) both showed a slight increase of 3 % and 2 %, respectively, both at 1 wt. % f-GNP loading. These enhancements are competitive with current literature results on nanocomposites, but at significantly lower filler content. We therefore demonstrated that f-GNPs are capable of providing effective toughening of epoxy resins, while maintaining other tensile and thermal properties.
References
Boland, C. S., Barwich, S., Khan, U., and J. N. Coleman, J. N. (2016). ‘High stiffness nanocomposite fibres from polyvinylalcohol filled with graphene and boron nitride’, Carbon, 99, 280–288.
Kausar, A., Anwar, Z., and B. Muhammad, B. (2016). ‘Recent developments in epoxy/graphite, epoxy/graphene, and epoxy/graphene nanoplatelet composites: a comparative review’, Polym. Plast. Technol. Eng., 55, 1192–1210.
Sainsbury, T., Gnaniah, S., Spencer, S. J., Mignuzzi, S., Belsey, N. A., Paton, K. R., Satti, A. (2016). ‘Extreme mechanical reinforcement in grapheme oxide based thin-film nanocomposites via covalently tailored nanofiller matrix compatibilization’, Carbon, 2016, 114, 367–376.
Stevens, B., Guin, T., Sarwar, O., John, A., Paton, K. R., Coleman, J. N., Grunlan, J. C. (2016). ‘Highly conductive graphene and polyelectrolyte multilayer thin films produced from aqueous suspension’, Macromol. Rapid Commun., 37, 1790–1794.
Tabandeh-Khorshid, M., Omrani, E., Menezes, P. L., Rohatgi, P. K. (2016). ‘Tribological performance of self- lubricating aluminium matrix nanocomposites: role of graphene nanoplatelets’, Eng. Sci. Technol. Int. J., 2016, 19, 463–469.
Boland, C. S., Khan, U., Ryan, G., Barwich, S., Charifou, R., Harvey, A., Backes, C., Z. Li, Z., Ferreira, M. S., Mobius, M. E., Young, R. J., Coleman, J. N. (2016). ‘Sensitive electromechanical sensors using viscoelastic graphenepolymer nanocomposites’, Science, 354, 1257–1260.
Liu, Y., Wu, H., Chen, G. (2016). ‘Enhanced mechanical properties of nanocomposites at low graphene content based on in situ ball milling’, Polym. Compos., 37, 1190–1197.
Dornbusch, M., Christ, U., Rasing, R. (2016). ‘Epoxy resins: fundamentals and applications. Reactive Polymers Fundamentals and Applications’, Vicenta Network.
Kemp, M. (2016). ‘Unlocking the potential of graphenes for the development of multi-scale composites – functionalization via plasma’, Reinf. Plastic., 60, 332–334.
Backes, C., Paton, K. R., Hanlon, D., Yuan, S., Katsnelson, M. I., Houston, J., Smith, R. J., McCloskey, D., Donegan, J.F., Coleman, J. N. (2016). ‘Spectroscopic metrics allow in situ measurement of mean size and thickness of liquid-exfoliated few-layer graphene nanosheets’, Nanoscale, 8, 4311–4323.
King, A. A., Davies, B. R., Noorbehesht, N., Newman, P., Church, T. L., Harris, A. T., Razal, J. M., Minett, A. I. (2016). ‘A new Raman metric for the characterisation of graphene oxide and its derivatives’, Sci. Rep., 6, 2824.
Li, Y., Zhang, H., Porwal, H., Huang, Z., Bilotto, E., Peijs, T. (2017). ‘Mechanical, electrical and thermal properties of in situ exfoliated graphene/epoxy nanocomposites’, Compos. Part A Appl. Sci. Manuf., 95, 229–236.
Mushtaq, A., Mukhtar H. B., Shariff, M. A .(2016). ‘Effect of glass transition temperature in enhanced polymeric blend membranes’, Procedia Eng., 148, 11–17.
Zagho, M. M., Hussein, E. A., and Elzatahry, A. A. (2018). “Recent overviews in functional polymer composites for biomedical applications,” Polymers, vol. 10, no. 7, p. 739, doi: 10.3390/polym10070739.
Darshan S. M., and Suresha, B. (2021). “Effect of basalt fiber hybridization on mechanical properties of silk fiber reinforced epoxy composites,” Materials Today: Proceedings, vol. 43, pp. 986–994, doi: 10.1016/j.matpr.2020.07.618.
Darshan, S. M., Suresha, B., and Jamadar, I. M. (2022). “Optimization of Abrasive Wear Parameters of Halloysite Nanotubes Reinforced Silk/Basalt Hybrid Epoxy Composites using Taguchi Approach,” Tribology in Industry, vol. 44, no. 1, pp. 253–267, doi: 10.24874/ti.1131.06.21.08.
Darshan S. M., and Suresha, B. (2022). “Effect of halloysite nanotubes on Physico-Mechanical Properties of Silk/Basalt fabric reinforced epoxy composites,” Materials Science Forum, vol. 1048, pp. 21–32, doi: 10.4028/www.scientific.net/msf.1048.21.
Namdev, A., Telang, A., and Purohit, R. (2022). “Experimental investigation on mechanical and wear properties of GNP/Carbon fiber/epoxy hybrid composites,” Materials Research Express, vol. 9, no. 2, p. 025303, doi: 10.1088/2053-1591/ac4e3f.
Vinod, Kumar, A., Suresha, B., Kumar, M., and Ramesh, S. (2018). “Study on Two Body Abrasive Wear behaviour of Carboxyl-Graphene Reinforced Epoxy Nano-composites,” IOP Conference Series: Materials Science and Engineering, vol. 376, p. 012058, doi: 10.1088/1757-899x/376/1/012058.
Namdev, A., Purohit, R., and A. Telang, A. (2023). “Impact of graphene nano particles on tribological behaviour of carbon fibre reinforced composites,” Advances in Materials and Processing Technologies, pp. 1–18, doi: 10.1080/2374068x.2023.2189670.
Namdev, A., Telang, A., Purohit, R., and M.K. Agrawal, M. K. (2022). “An experimental assessment of abrasive wear behavior of GNP/Carbon fiber/epoxy hybrid composites,” Indian Journal of Engineering and Materials Sciences, vol. 29, no. 6, pp. 777–785, doi: 10.56042/ijems.v29i6.70309.
Kumar, S., Singh, K. K., and Ramkumar, J. (2020). “The effects of graphene nanoplatelets on the tribological performance of glass fiber-reinforced epoxy composites,” Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology, vol. 235, no. 8, pp. 1514–1525, doi: 10.1177/1350650120965756.
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